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Benzenesulfonic acid-grafted UIO-66 with improved hydrophobicity as a stable Brønsted acid catalyst

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1389-1398 doi: 10.1007/s11705-022-2285-5

Abstract: -66 to introduce the hydrophobicity, as well as the Brønsted acidity, then assessed using catalytic hydrolysisof cyclohexyl acetate (to cyclohexanol) in water.UIO-66−PhSO3H promoted the conversion of cyclohexyl acetate at ca. 87%, and its activity and

Keywords： metal−organic frameworks (MOFs)     UIO-66     hydrolysis of cyclohexyl acetate     hydrophobicity     Brønsted acidity    

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Electricity-driven ammonia oxidation and acetate production in microbial electrosynthesis systems

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 4, doi: 10.1007/s11783-021-1476-5

Abstract:

• MES was constructed for simultaneous ammonia removal and acetate production

Keywords： Biocathode     Carbon dioxide     Electrochemical oxidation     Graphite anode     Boron-doped diamond    

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Durable and recyclable BiOBr/silk fibroin-cellulose acetate composite film for efficient photodegradation

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 11,   Pages 1765-1775 doi: 10.1007/s11705-023-2323-y

Abstract: A stable and recyclable of BiOBr/silk fibroin-cellulose acetate composite film was prepared by blending-wetThe cellulose acetate film modified by silk fibroin formed a finger-shaped porous structure, which provided

Keywords： BiOBr nanosheet     cellulose acetate     silk fibroin     photocatalytic degradation     dye wastewater    

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Methyl acetate–methanol mixture separation by extractive distillation: Economic aspects

Elena Graczová, Branislav Šulgan, Samuel Barabas, Pavol Steltenpohl

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 4,   Pages 670-682 doi: 10.1007/s11705-018-1769-9

Abstract:

Methyl acetate is considered low toxicity volatile solvent produced either as a by-product duringIn both cases, pure methyl acetate has to be isolated from the reaction mixture.Simulation of methyl acetate separation from its mixture with methanol by extraction distillation wasIts use in methyl acetate-methanol separation is presented in case study C.As high purity of dimethyl sulfoxide was required for the methyl acetate-methanol azeotrope breaking,

Keywords： methyl acetate     1-ethyl-3-methylimidazolium trifluoromethanesulfonate     extraction distillation     dimethyl    

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Kinetic studies of xylan hydrolysis of corn stover in a dilute acid cycle spray flow-through reactor

Hongman ZHANG, Qiang JIN, Rui XU, Lishi YAN, Zengxiang LIN

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 2,   Pages 252-257 doi: 10.1007/s11705-010-1010-y

Abstract: The hydrolysis of xylan to its monomeric xylose was modeled by a series of first-order reactions.Both biphasic and Saeman hydrolysis models were applied to fit the experimental data.The results confirmed that the kinetic data of xylan hydrolysis fitted a first-order irreversible reaction

Keywords： corn stover     xylan hydrolysis     biphasic model     Saeman model     cycle spray     kinetics    

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Research progress on hydrothermal dissolution and hydrolysis of lignocellulose and lignocellulosic waste

Yan ZHAO, Wenjing LU, Jiajun CHEN, Xiangfeng ZHANG, Hongtao WANG

Frontiers of Environmental Science & Engineering 2014, Volume 8, Issue 2,   Pages 151-161 doi: 10.1007/s11783-013-0607-z

Abstract: Previous studies have shown that pretreatment and hydrolysis are key processes for lignocellulose conversioncritically reviewed the progress done in the research and development of the hydrothermal dissolution and hydrolysisPrinciples, processes, and related studies on separate dissolution and asynchronous hydrolysis of lignin

Keywords： lignocellulosic waste     hydrothermal conversion     separate dissolution     asynchronous hydrolysis     mechanism    

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Catalytic hydrolysis of gaseous HCN over Cu–Ni/γ-Al

Linxia Yan, Senlin Tian, Jian Zhou, Xin Yuan

Frontiers of Environmental Science & Engineering 2016, Volume 10, Issue 6, doi: 10.1007/s11783-016-0872-8

Abstract: The Cu–Ni/γ-Al O catalyst was prepared to study HCN hydrolysis ?The presence of CO facilitates HCN hydrolysis and increases NH production. ?To examine further the efficiency of HCN hydrolysis, degradation products were analyzed.HCN hydrolysis.The presence of CO facilitates HCN hydrolysis andincreases NH production.

Keywords： Hydrogen cyanide     Cu–Ni/g-Al2O3     Catalytic hydrolysis    

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Establishment and verification of a shrinking core model for dilute acid hydrolysis of lignocellulose

Cunwen WANG, Xiaoling DUAN, Weiguo WANG, Zihao LI, Yuanhang QIN

Frontiers in Energy 2012, Volume 6, Issue 4,   Pages 413-419 doi: 10.1007/s11708-012-0212-z

Abstract: The kinetics of lignocellulose hydrolysis under the conditions of high temperature and dilute acid (masssugar concentration versus reaction temperature (170°C–220°C) and reaction time (150–1800 s) during the hydrolysis

Keywords： lignocellulose     dilute acid hydrolysis     shrinking core model    

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Characterization of value-added chemicals derived from the thermal hydrolysis and wet oxidation of sewage

Milan Malhotra, Anurag Garg

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 1, doi: 10.1007/s11783-020-1305-2

Abstract: . • Solids and carbon balance confirmed loss of organics during thermal hydrolysis. • Reaction pathwaysfor thermal hydrolysis and wet oxidation are proposed.We evaluated the effect of hydrothermal pretreatments, i.e., thermal hydrolysis (TH) and wet oxidation

Keywords： Hydrothermal pretreatment     Reaction kinetics     Reaction pathway     Sewage sludge     Thermal hydrolysis     Wet oxidation    

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Catalytic oxidation of carbon monoxide, toluene, and ethyl acetate over the

Zhidan Fu, Lisha Liu, Yong Song, Qing Ye, Shuiyuan Cheng, Tianfang Kang, Hongxing Dai

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 2,   Pages 185-196 doi: 10.1007/s11705-017-1631-5

Abstract: The effect of Pd loading on the catalytic oxidation of carbon monoxide, toluene, and ethyl acetate overand the temperature for 90% conversion was 55, 285 and 200 °C for oxidation of CO, toluene, and ethyl acetate

Keywords： cryptomelane-type manganese oxide octahedral molecular sieve     oxygen mobility     reducibility     carbon monoxide oxidation     volatile organic compound combustion    

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Microwave-assisted catalyst-free hydrolysis of fibrous cellulose for deriving sugars and biochemicals

Songshan Jiang, Helen Daly, Huan Xiang, Ying Yan, Huiping Zhang, Christopher Hardacre, Xiaolei Fan

Frontiers of Chemical Science and Engineering 2019, Volume 13, Issue 4,   Pages 718-726 doi: 10.1007/s11705-019-1804-5

Abstract: Microwave (MW) assisted catalyst-free hydrolysis of fibrous cellulose (FC, cellulolysis) at 200°C promoted

Keywords： microwave     fibrous cellulose     hydrolysis     sugars     mechanism    

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Dissolution and enzymatic hydrolysis of casein micelles studied by dynamic light scattering

LIU Rui, QI Wei, SU Rongxin, ZHANG Yubin, JIN Fengmin, HE Zhimin

Frontiers of Chemical Science and Engineering 2007, Volume 1, Issue 2,   Pages 123-127 doi: 10.1007/s11705-007-0023-7

Abstract: The effects of temperature, ionic strength, and enzymatic hydrolysis on the average hydrodynamic radiusThe value of casein increased rapidly during the process of enzymatic hydrolysis, and the structuralmodel of casein micelles in the enzymatic hydrolysis process was also proposed, i.e. the casein micelle

Keywords： compact     strength     temperature     regularly flocky     heating    

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Development of combined coagulation-hydrolysis acidification-dynamic membrane bioreactor system for treatment

Xue Shen, Lei Lu, Baoyu Gao, Xing Xu, Qinyan Yue

Frontiers of Environmental Science & Engineering 2019, Volume 13, Issue 1, doi: 10.1007/s11783-019-1093-8

Abstract:

• The system was composed of coagulation, hydrolysis

Keywords： Coagulation     Hydrolysis acidification     Dynamic membrane bioreactor     Polymer flooding    

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Energy-efficient recovery of tetrahydrofuran and ethyl acetate by triple-column extractive distillation

Ao Yang, Yang Su, Tao Shi, Jingzheng Ren, Weifeng Shen, Teng Zhou

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 2,   Pages 303-315 doi: 10.1007/s11705-021-2044-z

Abstract: triple-column extractive distillation process is developed for recovering tetrahydrofuran and ethyl acetate

Keywords： extractive distillation     solvent selection     conceptual design     process optimization     heat integration    

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Acceleration of the particulate organic matter hydrolysis by start-up stage recovery and its original

Yanqing Duan, Aijuan Zhou, Xiuping Yue, Zhichun Zhang, Yanjuan Gao, Yanhong Luo, Xiao Zhang

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 1, doi: 10.1007/s11783-020-1304-3

Abstract: . • The unique microbial communities facilitated the efficient hydrolysis of the POM. • ConsiderableTo address the availability of carbon sources for denitrification, the accelerated hydrolysis of theThe changes in soluble carbohydrates and proteins were monitored to investigate the hydrolysis performanceefficiency of POM was obtained, in contrast to that of WAS (3.4%), with a hydrolysis constant of 0.39Furthermore, the potential benefits and application of improved POM hydrolysis by start-up stage recovery

Keywords： Particulate organic matter (POM)     Hydrolysis     Microbial community     Mass balance    

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Title Author Date Type Operation

Benzenesulfonic acid-grafted UIO-66 with improved hydrophobicity as a stable Brønsted acid catalyst

Journal Article

Electricity-driven ammonia oxidation and acetate production in microbial electrosynthesis systems

Journal Article

Durable and recyclable BiOBr/silk fibroin-cellulose acetate composite film for efficient photodegradation

Journal Article

Methyl acetate–methanol mixture separation by extractive distillation: Economic aspects

Elena Graczová, Branislav Šulgan, Samuel Barabas, Pavol Steltenpohl

Journal Article

Kinetic studies of xylan hydrolysis of corn stover in a dilute acid cycle spray flow-through reactor

Hongman ZHANG, Qiang JIN, Rui XU, Lishi YAN, Zengxiang LIN

Journal Article

Research progress on hydrothermal dissolution and hydrolysis of lignocellulose and lignocellulosic waste

Yan ZHAO, Wenjing LU, Jiajun CHEN, Xiangfeng ZHANG, Hongtao WANG

Journal Article

Catalytic hydrolysis of gaseous HCN over Cu–Ni/γ-Al

Linxia Yan, Senlin Tian, Jian Zhou, Xin Yuan

Journal Article

Establishment and verification of a shrinking core model for dilute acid hydrolysis of lignocellulose

Cunwen WANG, Xiaoling DUAN, Weiguo WANG, Zihao LI, Yuanhang QIN

Journal Article

Characterization of value-added chemicals derived from the thermal hydrolysis and wet oxidation of sewage

Milan Malhotra, Anurag Garg

Journal Article

Catalytic oxidation of carbon monoxide, toluene, and ethyl acetate over the

Zhidan Fu, Lisha Liu, Yong Song, Qing Ye, Shuiyuan Cheng, Tianfang Kang, Hongxing Dai

Journal Article

Microwave-assisted catalyst-free hydrolysis of fibrous cellulose for deriving sugars and biochemicals

Songshan Jiang, Helen Daly, Huan Xiang, Ying Yan, Huiping Zhang, Christopher Hardacre, Xiaolei Fan

Journal Article

Dissolution and enzymatic hydrolysis of casein micelles studied by dynamic light scattering

LIU Rui, QI Wei, SU Rongxin, ZHANG Yubin, JIN Fengmin, HE Zhimin

Journal Article

Development of combined coagulation-hydrolysis acidification-dynamic membrane bioreactor system for treatment

Xue Shen, Lei Lu, Baoyu Gao, Xing Xu, Qinyan Yue

Journal Article

Energy-efficient recovery of tetrahydrofuran and ethyl acetate by triple-column extractive distillation

Ao Yang, Yang Su, Tao Shi, Jingzheng Ren, Weifeng Shen, Teng Zhou

Journal Article

Acceleration of the particulate organic matter hydrolysis by start-up stage recovery and its original

Yanqing Duan, Aijuan Zhou, Xiuping Yue, Zhichun Zhang, Yanjuan Gao, Yanhong Luo, Xiao Zhang

Journal Article